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教授
Eric A. B. Kantchev
发布时间:2018-11-17    阅读次数:114
姓 名:
Eric A. B. Kantchev
职 称:
教授
职 务:
 
所属系:
应用化学系
邮 箱:
ekantchev@hfut.edu.cn, ekantchev@gmail.com
电 话:
 

个人简历

学习经历
1997-1991 High School of Mathematics and Science "Ivan Gyuzelev", Gabrovo, Bulgaria
1991-1996 Diploma (M. Sci.) Faculty of Chemistry, University of Sofia, Sofia, Bulgaria
1997-2001 Ph. D. Department of Chemistry, The Ohio State University, Columbus, OH, USA
研究经历
2001-2004 Postdoctoral Research Fellow, Institute of Chemistry, Academia Sinica, Taipei, Taiwan
2004-2005 Senior Postdoctoral Research Fellow, Department of Chemistry, York University, Toronto, ON, Canada
2005-2009 Research Scientist II, Institute of Bioengineering and Nanotechnology, A*STAR, Singapore
2009 Research Scientist II, Forma Therapeutics, Singapore
2010-2013 Research Scientist III, Institute of Materials Research and Engineering, A*STAR, Singapore
2013-2014 Visiting Professor, School of Materials Science and Engineering, Nanyang Technological University, Singapore
2014 Visiting Researcher, School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan, China

主要研究领域、方向

课题组主页—http://121.251.19.227/_s181/main.psp
Mechanistic and synthetic studies and molecular design of organic and organometallic molecules and materials.

研究成果(代表性成果)

1. 1999-present: Publications: 42; Total citations: 2062 (as of 01.05.2014); h-index: 19. Conference Proceedings: 4. Book chapters: 3.
2.  Referee for Chemical Communications, Organic and Biomolecular Chemistry, Physical Chemistry Chemical Physics,  RSC Advances, New Journal of Chemistry, Chemistry - A European Journal, Organometallics, Tetrahedron Letters, Tetrahedron Asymmetry.
3. 2007-present: More than 30 invited and international conference lectures.
4.2008:  Young Industrial Investigator Award, ACS
5.1991: XXIII International chemistry Olympiad, silver medal.
6: Research funding from NSERC Canada (2004-2005) and A*STAR Singapore (2005-2013): >3 000 000 Chinese yuan. 2010-present: Computational chemistry support by A*STAR Computational Resource Center (HPC Linux clusters).
7. (Co-)Development and commercialization of N-heterocyclic carbene-palladium catalysts for cross-coupling reactions:  PEPPSI (2004-2005) and SingaCycle (2005-2009).

目前承担科研项目

1. Mechanistic studies and molecular design of sulfoxide ligands for Rh-, Pd-, Ru- and Ir-catalyzed transformations, including asymmetric reactions.
2. Computational studies of transition metal-catalyzed reactions.
3. Development of novel  boron reagents for multi-step organic transformations.
4. Design and synthesis of novel organic optical and electronic materials and dyes.

获奖及专利情况

Patents
1.Organ, M. G.; O'Brien, C. J.; Kantchev, E. A. B. "Transition metal complexes of N-heterocyclic carbenes, Method of preparation and use in transition metal catalyzed organic transformations" US7,250,510 B2, 60/817,343, 60/710,487 and 11/508 334, Canadian Pat. 2,551,412 and 2,556,850.
2.Ying, J. Y.; Yu, H.-H.; Ali, E. M.; Kantchev, E. A. B. “Electrically conducting polymers and their use in sensors” WO2008/039151, US2010/0048815, US8,114,955.
3.Ying, J.Y.; Kantchev, E. A. B. “N-Heterocyclic carbene metallacycle catalysts and methods” WO2008/156451, EP 2 079 750, US 2010/0197920, US 8,492,552.
4.Ying, J. Y.; Yu, H.-H.; Luo, S.-C.; Xie, H.; Kantchev, E. A. B. “Functionalized poly(3,4-alkylenebridgedthiophene) useful for bionanointerfaces for controlled adhesion of a biological molecule” WO 2009/054814.
5. Yu, H.-H.; Ying, J. Y.; Tansil, N. C.; Kantchev, E. A. B. “DNA complexing agents” US2010/0126880

著作论文(代表作)

Corresponding author publications:
01. Peh, G.-R.; Kantchev, E. A. B.; Zhang, C.; Ying, J. Y. “N-Heterocyclic carbene (NHC)-ligated cyclopalladated N,N-dimethylbenzylamine: A highly active, practical and versatile Heck-Mizoroki precatalyst” Org. Biomol. Chem. 2009, 7, 2110-2119.
02. Peh, G.-R.; Kantchev, E. A. B.; Er, J.-C.; Ying, J. Y. “Rational exploration of N-heterocyclic carbene (NHC)-palladacycle diversity: A highly active and versatile precatalyst for Suzuki-Miyaura couplings of deactivated aryl- and alkyl substrates” Chem. Eur. J. 2010, 16, 4010-4017.
03. Chass, G. C.; Kantchev, E. A. B.; Fang, D. C. “The fine balance between one cross-coupling and two -hydride elimination pathways: A high level DFT (SCRF=PCM) mechanistic investigation of Ni(-allyl)2-catalyzed cross-coupling of alkyl halides and alkyl Grignard reagents” Chem. Commun. 2010, 46, 2727-2729.
04. Kantchev, E. A. B. “The origin of regio- and enantioselectivity in the Rh/chiral 1,4-diene catalyzed addition of phenylboronic acid to enones: Insights from DFT” Chem. Commun. 2011, 47, 10969-10971.
05. Kantchev, E. A. B.; Tan, H. S.; Norsten, T. B.; Sullivan, M. B. “O,O´-Disubstituted N,N´-dihydroxynaphthalenediimides (DHNDI): First principles designed organic building blocks for materials science” Org. Lett. 2011, 13, 5432-5435.
06. Kantchev, E. A. B.; Norsten, T. B. Sullivan, M. B. “Chemically accurate and computationally-efficient time-dependent density functional theory (TD-DFT) modelling of the UV/Vis spectra of Pechmann dyes and related compounds” Proc. Comp. Sci. 2011, 4, 1157-1166.
07. Sasaki, K. Nishimura, T.; Shintani, R.; Kantchev, E. A. B., Hayashi, T. “Rhodium/diene-catalyzed tandem 1,4-shift/1,4-addition of (E)-1,2-diphenylethenylboronic acid to enones: density functional theory modelling and asymmetric catalysis” Chem. Sci. 2012, 3, 1278-1283.
08. Luo, S. C.; Kantchev, E. A. B.; Zhu, B.; Siang, W.-V.; Yu, H.-H. “Tuneable, dynamic and electrically stimulated lectin-carbohydrate recognition on a glycan-grafted conjugated polymer” Chem. Commun. 2012, 48, 6942-6944.
09. Kantchev, E. A. B.; Norsten, T. B.; Sullivan, M. B. “Time-dependent density functional theory (TDDFT) modelling of Pechmann dyes: from accurate absorption maximum prediction to virtual dye screening” Org. Biomol. Chem. 2012, 6682-6692.
10. Liu, H.-J.; Kantchev, E. A. B.; Tan, H.-S.; Norsten, T. B. “Structural, electronic and optical properties of thiophene & thienothiophene containing diketo-pyrrolo-pyrroles (DPPs) in polar aprotic solvents” J. Mol. Eng. Mater., 2013, 1, 1250003.
11. Kantchev, E. A. B. “Cooperativity between steric repulsion and crossed diene coordination governs the enantioselectivity in rhodium(i)/chiral, 1,4- and 1,5-diene-catalysed 1,4-addition reaction: a DFT study” Chem. Sci. 2013, 4, 1864-1875.
12. Qin, H.-L.; Han, J.-B.; Hao, J.-H.; Kantchev, E. A. B. “Computational and experimental comparison of diphosphane and diene ligands in the Rh-catalysed carboxylation of organoboron compounds with CO2” Green Chem.  2014, 16, 3224-3229.
13. Qin, H.-L.; Chen, X.-Q.; Huang, Y.-Z.; Kantchev, E. A. B. "A first-principles examination of the asymmetric induction model in the binap/Rh(I)-catalyzed 1,4-addition of phenylboronic acid to cyclic enones by DFT calculations" Chem. Eur. J. 2014, 20, accepted; doi: 10.1002/chem.201402451


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